000			03433nam a2200361 a 4500
001			ebr10575437
003			CaPaEBR
006			m u
007			cr cn|||||||||
008			120206s2012 njuad sb 001 0 eng d
010			_z 2012000246
020			_z9781118026090 (pbk.)
020			_z9780470666272
020			_z9781118299739 (e-book)
040			_aCaPaEBR _cCaPaEBR
035			_a(OCoLC)775591921
050	1	4	_aQD181.P1 _bP46 2012eb
082	0	4	_a546/.712595 _223
245	0	0	_aPhosphorus(III) ligands in homogeneous catalysis _h[electronic resource] : _bdesign and synthesis / _cedited by Paul Kamer and Piet W.N.M. van Leeuwen.
260			_aHoboken, N.J. : _bWiley, _c2012.
300			_axviii, 547 p. : _bill.
504			_aIncludes bibliographical references and index.
520			_a"Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals.This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis.Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation.Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands.Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice.Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry"-- _cProvided by publisher.
533			_aElectronic reproduction. _bPalo Alto, Calif. : _cebrary, _d2011. _nAvailable via World Wide Web. _nAccess may be limited to ebrary affiliated libraries.
650		0	_aPhosphorus compounds.
650		0	_aLigands.
650		0	_aCatalysis.
655		7	_aElectronic books. _2local
700	1		_aKamer, Paul.
700	1		_aLeeuwen, P. W. N. M. van _q(Piet W. N. M.)
710	2		_aebrary, Inc.
856	4	0	_uhttp://site.ebrary.com/lib/rucke/Doc?id=10575437 _zAn electronic book accessible through the World Wide Web; click to view
999			_c78106 _d78106